Scientific Study
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Products: Almonds
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Almond Shell-Derived, Biochar-Supported, Nano-Zero-Valent Iron Composite for Aqueous Hexavalent Chromium Removal: Performance and Mechanisms.
Authors: Shu, Y., Ji, B., Cui, B., Shi, Y., Wang, J., Hu, M., ... & Guo, D.
- Journals: Nanomaterials (Basel)
- Pages: 198
- Volume: 10(2)
- Year: 2020
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Nano-zero-valent iron biochar derived from almond shell (nZVI-ASBC) was used for hexavalent chromium (CR) removal. Experiments showed that pH was the main factor (p < 0.01) that affected the experimental results. At a dosage of 10 mg·L-1 and pH of 2-6, in the first 60 min, nZVI-ASBC exhibited a removal efficiency of 99.8%, which was approximately 20% higher than the removal yield at pH 7-11. Fourier transform infrared spectroscopy results indicated N-H was the main functional group that influenced the chemisorption process. The pseudo second-order dynamics and Langmuir isotherm models proved to be the most suitable. Thermodynamic studies showed that the reaction was exothermic and spontaneous at low temperatures (T < 317 K). Various interaction mechanisms, including adsorption and reduction, were adopted for the removal of Cr(VI) using the nZVI-ASBC composite. The findings showed that the BC-modified nZVI prepared with almond shell exerts a good effect and could be used for the removal of Cr(VI).